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1. One atomic mass unit in kilogram is

(a) 1/N_{A}

(b) 12/N_{A}

(c)1/1000 N_{A}

(d) 1000/N_{A}

## Answer

Answer: (c)

2. If 50 gm oleum sample rated as 118% is mixed with 18 gm water, then the correct option is

(a) The resulting solution contains 18 gm of water and 118 gm H_{2}SO_{4}

(b) The resulting solution contains 9 gm water and 59 gm H_{2}SO_{4}

(c) The resulting solution contains only 118 gm pure H_{2}SO_{4}

(d) The resulting solution contains 68 gm of pure H_{2}SO_{4}

## Answer

Answer: (b)

3. The density of a solution containing 40% by mass of HCl is 1.2 g/mL. Calculate the molarity of the solution.

(a) 13.15

(b) 13.25

(c) 13.13

(d) 13.18

## Answer

Answer: (a)

4. Units of parts per million (ppm) or per billion (ppb) are often used to describe the concentrations of solutes in very dilute solutions. The units are defined as the number of grams of solute per million or per billion grams of solvent. Bay of Bengal has 1.9 ppm of lithium ions. What is the molality of Li^{+} in this water ?

(a) 2.7 × 10^{-4}

(b) 2.7 × 10^{-5}

(c) 2.7 × 10^{-6}

(d) 2.7 × 10^{-7}

## Answer

Answer: (a)

5. What is the concentration of chloride ion, in molarity, in a solution containing 10.56 gm BaCl_{2}.8H_{2}O per litre of solution ? (Ba = 137)

(a) 0.06 M

(b) 0.006 M

(c) 0.6 M

(d) 0.600 M

## Answer

Answer: (a)

6. The concentration of a solution is 8% (w/w) and 10% (w/v). Calculate density of solution?

(a) 1.25 gm/ml

(b) 1.15 gm/ml

(c) 1.35 gm/ml

(d) 1.05 gm/ml

## Answer

Answer: (a)

7. The concentration of Ca(HCO_{3})_{2} in a sample of hard water is 500 ppm. The density of water sample is 1.0 gm/ml. Calculate the molarity of solution?’

(a) 3.086 × 10^{-3} M

(b) 3.086 × 10^{-5} M

(c) 3.086 × 10^{-8} M

(d) 3.086 × 10^{-2} M

## Answer

Answer: (a)

8. How much BaCl_{2} would be needed to make 250 ml of a solution having the same concentration of Cl^{–} as one containing 3.78 gm NaCl per 100 ml ? (Ba = 137)

(a) 16.8 gm

(b) 16.9 gm

(c) 15.8 gm

(d) 15.9 gm

## Answer

Answer: (a)

9. Find out the volume of 98% w/w H_{2}SO_{4} (density = 1.8 gm/ ml), must be diluted to prepare 12.5 litres of 2.5 M sulphuric acid solution.

(a) 1.736 litre

(b) 1.636 litre

(c) 1.536 litre

(d) 1.436 litre

## Answer

Answer: (a)

10. 560 gm of 2 ‘m’ aqueous solution of urea is mixed with 2480 gm of 4 ‘m’ aqueous solution of urea. Calculate the molality of the resulting solution?

(a) 3.6 m

(b) 2.6 m

(c) 6.6 m

(d) 5.6 m

11. When V ml of 2.2 M H_{2}SO_{4}, solution is mixed with 10 V ml of water, the volume contraction of 2% take place. Calculate the molarity of diluted solution ?

(a) 0.204 M

(b) 0.404 M

(c) 0.304 M

(d) 0.004 M

## Answer

Answer: (a)

12. What volume of 0.8 M AICI_{3} solution should be mixed with 50 ml of 0.2M CaCl solution to get solution of chloride ion concentration equal to 0.6 M ?

(a) 5.56 ml

(b) 5.66 ml

(c) 5.06 ml

(d) 5.86 ml

## Answer

Answer: (a)

13. 500 ml of a H_{2}O_{2} solution on complete decomposition produces 2 moles of H_{2}O. Calculate the volume strength of H_{2}O_{2} solution? [Given : Volume of O_{2} is measured at latm and 273 K]

(a) 44.8 V

(b) 42.8 V

(c) 43.8 V

(d) 48.8 V

## Answer

Answer: (a)

14. Find the mass of KOH needed to prepare 100 ml 1 M KOH solution. [At. mass K = 39]

(a) 5.6 g

(b) 5.5 g

(c) 5.7 g

(d) 6.6 g

## Answer

Answer: (a)

15. Mole fraction of A in H_{2}O is 0.2. The molality of A in H_{2}O is :

(a) 13.9

(b) 13.8

(c) 12.9

(d) 12.88

## Answer

Answer: (a)

16. The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having 1000 gm of solvent.

(a) 1019.6 g

(b) 1018.6 g

(c) 1017.6 g

(d) 1029.6 g

## Answer

Answer: (a)

17. 3.0 litre of water are added to 2.0 litre of 5 M HCI. What is the molarity of HCI in the resultant solution?

(a) 2M

(b) 3 M

(c) 4 M

(d) 5 M

## Answer

Answer: (a)

18. What is the molarity of H_{2}SO_{4} solution that has a density of 1.84 g/cc and contains 98% by mass of H_{2}SO_{4} ? (Given atomic mass of S = 32)

(a) 18.4 M

(b) 18.5 M

(c) 17.5 M

(d) 18.3 M

## Answer

Answer: (a)

19. The percentage by mole of NO_{2} in a mixture of NO_{2}(g) and NO(g) having average molecular mass 34 is:

(a) 25%

(b) 20%

(c) 40%

(d) 75%

## Answer

Answer: (a)

20. The number of g-molecules of oxygen in 6.02 × 10^{24} CO molecules is

(a) 1 g-molecule

(b) 0.5 g-molecule

(c) 5 g-molecule

(d) 10 g-molecule

## Answer

Answer: (c)

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